Decomposition of Aqueous Hydrogen Peroxide by Oxidized Chromia-Alumina Catalysts

Effect of hydrogen peroxide on the decomposition of monochlorophenols by sonolysis in aqueous solution.

The decomposition rates of several monochlorophenol by sonolysis were enhanced by the presence of hydrogen peroxide. An optimum concentration of hydrogen peroxide was observed for achieving maximum sonolysis rate of monochlorophenol. The decomposition rates of 3-chlorophenol by sonolysis were higher than those for 2- and 4-chlorophenol for most experiments conducted, suggesting that the ring st...

CO x Free Hydrogen Production by Catalytic Decomposition of Methane Over Porous Ni/Al2O3 Catalysts

Densification characteristics of chromia/alumina castables by particle size distribution

The quality of the refractories applied on integrated gasification combined cycle should be a key factor that affects both the reliability and the economics of gasifier operation. To enhance the workability of chromia/alumina castables, three types of ultrafine alumina powder were added to improve the workability. Densification behavior of such castables in the presence of ultrafine alumina was...

How Hydrogen Peroxide Is Metabolized by Oxidized Cytochrome c Oxidase

In the absence of external electron donors, oxidized bovine cytochrome c oxidase (CcO) exhibits the ability to decompose excess H2O2. Depending on the concentration of peroxide, two mechanisms of degradation were identified. At submillimolar peroxide concentrations, decomposition proceeds with virtually no production of superoxide and oxygen. In contrast, in the millimolar H2O2 concentration ra...

Cyclopentadienyl-silsesquioxane titanium complexes: highly active catalysts for epoxidation of alkenes with aqueous hydrogen peroxide.

Titanium complexes bearing an unprecedented tridentate cyclopentadienyl-silsesquioxanate ligand provide a new class of efficient and selective catalysts for epoxidation of olefins with aqueous hydrogen peroxide under homogeneous conditions.